Joyce
  I have   found that Lime-A-Way works pretty well, but for your longtime buildup you may   need to go heavier duty.
I had   rust spots on a metal outside door. The mgr at Sherwin Williams told me to   prepare for painting using a product they carry called OSPHO by Skyco. It was   pricey, but it's 32 oz and lasts and lasts for use elsewhere. I did balk at   paying so much, but I still have half of it left and it has been worth every   penny. Sorry I don't recall the price. You may find it cheaper   online.
  Getting   calcium off the water line in my 3 toilets has been the bane of my   existence...well, one of them anyway. I tried the phospho on them and my toilets   gleamed like they've been to the dental hygienist
  . Have also used on bathroom sinks and   other rust spots here and there. It has cleaned the messy stuff off my shower   doors and side glass.
As you might guess from the name, it is   phosphoric acid. Sounds like this is the way to go for your longtime buildup.   Then maybe you can keep it clean with regular cleaning using CLR or Lime-Away. I   think you'll be amazed at how easy the job is when you use the Ospho. And you   don't need to worry about using a thickener. Having just come back from an awful   plumber bill after overloading my system, I'd be really careful about what goes   down the drain.
Good luck and keep us   posted.
Carol
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