I like to avoid chemicals too. I used this homemade recipe found on-line and it worked like a charm!
1 quart household vinegar, 1/4 cup salt, 2 teaspoons liquid dish detergent (only use a detergent that contains no bleach). Mix together and spray.
Also, just rock salt dissolved in water or added straight works. But use this only where you want to kill all--like driveways or walks.
Good luck.
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